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It has been shown to reduce damage to the energy producing mitochondria

The taste of heavy metals: gene regulation by mtf-1

titled Glutathione Stimulates Vitamin D Regulatory and Glucose-Metabolism Genes, Lowers Oxidative Stress and Inflammation, and Increases 25 OHD Levels in Blood: A Novel Approach to Treat 25-Hydroxyvitamin D Deficiency clearly outlines this relationship and describes how increasing GSH has been shown to increase the bioavailability of 25(OH)D

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Passardi F, Theiler G, Zamocky M, Cosio C, Rouhier N, Teixera F, Margis-Pinheiro M, Ioannidis V, Penel C, Falquet L, Dunand C (2007) PeroxiBase: the peroxidase database