The D-Ala substitution provides dual benefits: modest intrinsic potency enhancement (3-fold in vitro) plus substantial protection against dipeptidylpeptidase IV (DPP-IV) degradation, which normally cleaves between positions 2 and 3
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Rossignol DA, Bradstreet JJ
Zou X, Feng Z, Li Y, Wang Y, Wertz K, Weber P, Fu Y, Liu J